Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N2.
نویسندگان
چکیده
Two molybdenum dinitrogen complexes with a novel pentaphosphine environment have been synthesised and structurally characterised. A combination of the tripodal alkylphosphine ligand tris(dimethylphosphinomethyl)methylsilane (SiP3) and the coligands dppm/dmpm has been employed to tune the activation of the N2 ligand.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 5 شماره
صفحات -
تاریخ انتشار 2014